FIELD: chemistry.
SUBSTANCE: invention relates to heterogeneous catalysis. Described is a catalyst for decomposing chlorine-containing hydrocarbons or mixtures thereof, containing dispersed active particles of nickel attached to carbon fibres with diameter 0.1-0.4 mcm. Described also is a method of preparing the described catalyst, characterised by that the starting raw material for preparing said catalyst is solid articles made from nickel, for example in form of a tape, wire etc, and pairs of halogen-substituted hydrocarbons in a mixture with hydrogen are used to mould dispersed active particles from solid metal articles. Described also is a method of decomposing chlorine-containing hydrocarbons or mixtures thereof, involving catalytic conversion of thereof into carbon, hydrogen chloride and hydrogen in the presence of the described catalyst.
EFFECT: catalyst is resistant to deactivation in aggressive conditions and provides high output of carbon fibres during decomposition of chlorine-containing hydrocarbons or mixtures thereof.
11 cl, 2 tbl, 3 dwg, 12 ex
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Authors
Dates
2011-10-20—Published
2010-04-30—Filed