METHOD OF PREPARING OXIDE-POLYMETALLIC CATALYSTS BASED ON HEAT-RESISTANT ALLOYS FOR PARTIAL OXIDATION OF HYDROCARBONS INTO SYNTHESIS-GAS Russian patent published in 2015 - IPC B01J37/08 B01J37/00 B01J23/882 B01J23/883 B01J23/89 B01J23/83 B01J21/04 B01J21/06 C01B3/34 C01B3/38 B82B3/00 

Abstract RU 2552639 C1

FIELD: chemistry.

SUBSTANCE: invention relates to method of preparing oxide-polymetallic catalysts, containing metals of platinum group, for oxidative-vapour conversion of hydrocarbons with obtaining carbon oxide and hydrogen. Method includes processing NiO and CO3O4 with solutions of nitrates Al, Ce, Zr and compounds of palladium Pd(NH3)4Cl2, platinum H2[PtCl6]·6H2O and rhodium H3[RhCl6], with the following drying; coking obtained material in methane flow at 550°C, obtaining paste from said material, pseudoboehmite and tetraisopropoxylane, filling foam-nichrome pores with suspension from obtained material, removal of water at 80°C, calcinations for 3 hours in argon atmosphere at 1300°C, removal of carbon with water vapours at 600°C for 3 hours.

EFFECT: creation of highly efficient heterogeneous catalyst.

4 cl, 7 tbl, 4 ex

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RU 2 552 639 C1

Authors

Dolinskij Sergej Ehrikovich

Usachev Nikolaj Jakovlevich

Pleshakov Andrej Mikhajlovich

Dates

2015-06-10Published

2013-11-19Filed