FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing ethylene and propylene using starting material having high concentration of diolefins by bringing hydrocarbon substance containing at least one olefin which contains 4-12 carbon atoms in amount of at least 20 wt % and where the hydrocarbon substance contains at least one diolefin compound containing 3-12 carbon atoms in amount of 1.26-2.5 wt % in terms of the weight of the hydrocarbon substance, into contact with a zeolite-containing moulded catalyst in a reactor for catalytic conversion of at least one olefin containing 4-12 carbon atoms, where the zeolite in the zeolite-containing moulded catalyst satisfies conditions (1), (2), (3) and (4): (1) the zeolite is an intermediate pore size zeolite with pore size from 5 to 6.5 Е, (2) the amount of protons in the zolite is equal to or less than 0.02 mmol per gram of zeolite, (3) the zeolite contains at least one metal selected from a group comprising group IB metals, (4) the zeolite has molar ratio of silicon oxide to aluminium oxide (SiO2/Al2O3) ranging from 800 to 2000.
EFFECT: method enables stable production of ethylene and propylene with high output using raw material which contains diolefin.
7 cl, 3 ex, 4 tbl, 1 dwg
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Authors
Dates
2011-11-10—Published
2006-09-14—Filed