FIELD: chemistry.
SUBSTANCE: described is a catalyst system for producing propylene copolymers, in which the weight ratio of the comonomer to the sum of monomers present in said polypropylene copolymer (comonomer/(comonomer + propylene)) is equal to at least 2.0 wt %, containing (a) procatalyst composition containing (i) a group 4-6 transition metal compound (IUPAC, Nomenclature of inorganic chemistry, 1989), (ii) MgCl2 and (iii) an intrinsic donor in which said intrinsic donor contains diethyl phthalate, and (b) an extrinsic donor which is diisopropyl diethoxy silane (DIPDES), and (c) an organometallic cocatalyst. The invention describes a method of producing the described catalyst system in which a procatalyst is obtained at the first step and an extrinsic donor and a cocatalyst are added at the second step. The invention also describes propylene copolymers obtained in the presence of the described catalyst system.
EFFECT: high-strength propylene copolymers are obtained.
21 cl, 9 tbl, 25 dwg, 4 ex
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Authors
Dates
2011-12-20—Published
2008-05-21—Filed