FIELD: chemistry.
SUBSTANCE: invention refers to the method of producing new enantiomerically rich complexes of cyclopentadienyl-1-neomenthyl-4,5,6,7-tetrahydroindenyl zirconium alkyl chloridesof the common formula (1 a, b) 
, where R = Et, n-Bu. Method involves reaction of cyclopentadienyl-1-neomenthyl-4,5,6,7-tetrahydroindenyl zirconium dichloride (π-complex) with alkyllithium RLi, where R is described above, in molar ratio π-complex: RLi=1:(0.8-1.2) in argon at -78°C, in toluene and then raising temperature to room temperature and stirring for 20 minutes.
EFFECT: obtaining novel enantiomerically rich complexes of cyclopentadienyl-1-neomenthyl-4,5,6,7-tetrahydroindenyl zirconium alkyl chlorides with a chiral centre at the zirconium atom, which can be used as a component of catalyst systems.
2 ex, 1 tbl
| Title | Year | Author | Number |
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| METHOD OF OBTAINING ENANTIOMERICALLY ENRICHED η-UMINOACYL NEOMENTYL-SUBSTITUTED COMPLEXES WITH CHIRAL CENTRE ON Zr" | 2012 |
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| METHOD OF PRODUCING OPTICALLY ACTIVE COMPLEX OF CYCLOPENTADIENYL-1-NEOMENTHYL-4,5,6,7-TETRAHYDROINDENYLZIRCONIUM DIMETHYL | 2007 |
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| METHOD OF PRODUCING 1-DIMETHYLALUMINIUM-2-METHYLALKANES | 2008 |
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| ORGANOMETALLIC COMPOUND SUITABLE AS COCATALYST IN POLYMERIZATION OF OLEFINS | 2001 |
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| METALLOCENE CATALYST AND METHOD OF PREPARATION OF POLYOLEFINS | 1994 |
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