METHOD OF PRODUCING OPTICALLY ACTIVE COMPLEX OF CYCLOPENTADIENYL-1-NEOMENTHYL-4,5,6,7-TETRAHYDROINDENYLZIRCONIUM DIMETHYL Russian patent published in 2010 - IPC C07F7/00 

Abstract RU 2382045 C2

FIELD: chemistry.

SUBSTANCE: invention relates to organometallic synthesis, and specifically to a method of producing a novel optically active π-complex of zirconium with general formula , involving reaction of a dichloride π-complex of zirconium with methyllithium, with molar ratio π-complex:MeLi=1:2, in an argon atmosphere at temperature -78°C, in diethyl ether with subsequent increase of temperature to room temperature. The method is distinguished by that, the dichloride π-complex of zirconium used is cyclopentadienyl-1-neomenthyl-4,5,6,7-tetrahydroindenylzirconium dichloride and the reaction is carried out for 12 hours.

EFFECT: said method can be used as a component of a catalyst system in processes of stereoselective poly- and oligomerisation of unsaturated compounds, and in fine organic and organometallic synthesis.

1 cl, 1 ex

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RU 2 382 045 C2

Authors

Parfenova Ljudmila Vjacheslavovna

Pechatkina Svetlana Vital'Evna

Berestova Tat'Jana Vjacheslavovna

Uitbi Richard

Khalilov Leonard Mukhibovich

Dzhemilev Usein Memetovich

Dates

2010-02-20Published

2007-10-10Filed