FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing methylene-hem-diaryloxycyclopropanes, which are used as corrosion inhibitors, as well as reagents in organic synthesis. The method involves O-alkylation of corresponding substituted phenols with chloromethyl-hem-dichlorocyclopropanes in dimethyl sulphoxide in microwave radiation conditions in the presence of an interphase catalyst Catamin AB and aqueous sodium hydroxide solution for 40 minutes.
EFFECT: method enables to obtain desired products with high output and prevents formation of by-products.
1 tbl, 4 ex
Title | Year | Author | Number |
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METHOD OF OBTAINING CIS-2,3-DIALKOXYMETHYL-1,1-DICHLOROCYCLOPROPANES | 2013 |
|
RU2538607C1 |
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|
RU2430903C1 |
METHOD OF OBTAINING 1,3-DIOXOLANES, CONTAINING GEM-DICHLOROCYCLOPROPYL SUBSTITUENT | 2012 |
|
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RU2620268C1 |
METHOD OF PRODUCING 2-(DICHLOROMETHYL)-2-(GEM-DICHLOROCYCLOPROPYL)-1,3-DIOXACYCLOALKANES | 2012 |
|
RU2494097C1 |
METHOD OF OBTAINING 3-(CHLOROMETHYL)-3-(ALKOXYMETHYL)OXETANES | 2013 |
|
RU2536687C1 |
METHOD OF PRODUCING 5-(CHLOROMETHYL)-5-(ALKOXYMETHYL)-1,3-DIOXANES | 2013 |
|
RU2537320C1 |
METHOD OF PRODUCING 1-PHENOXY-2,2-DICHLOROCYCLOPROPANE | 2010 |
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RU2443672C1 |
Authors
Dates
2012-01-27—Published
2010-07-14—Filed