METHOD OF OBTAINING AMINES Russian patent published in 2014 - IPC C07C317/28 A01N43/28 A01P13/00 

Abstract RU 2530891 C1

FIELD: chemistry.

SUBSTANCE: method consists in alkylation of the primary amine, selected from benzilamine or amylamine, with 4-chloromethyl-1,3-dioxolane in the presence of a catalyst with the molar ratio of components: primary amine: 4-chloromethyl-1,3-dioxolane: catalyst =1:0.8:0.06 until the secondary amine N-alkyl-(1,3-dioxolan-4-ylmethyl)amine is obtained. The obtained secondary amine is alkylated with 2-chloromethyl-hem.-dichlorocyclopropane with a molar ratio N-alkyl-(1,3-dioxolan-4-ylmethyl)amine: 2-chloromethyl-hem.-dichlorocyclopropane =3:1. As the catalyst in obtaining the secondary amine, triethylbenzylammonium chloride (TEBAC) is preferably applied.

EFFECT: novel tertiary amines, possessing herbicidal properties.

2 cl, 1 tbl, 1 ex

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RU 2 530 891 C1

Authors

Zlotskij Semen Solomonovich

Kazakova Anna Nikolaevna

Kras'Ko Svetlana Anatol'Evna

Mikhajlova Natal'Ja Nikolaevna

Aminova Ehl'Mira Kurbangalievna

Dates

2014-10-20Published

2013-05-07Filed