FIELD: metallurgy.
SUBSTANCE: method for obtaining cobalt and its compounds involves conversion of cobalt from cobalt-bearing raw material to the solution; deposition of cobaltic hydroxide (III) using oxidiser and neutraliser, dilution of cobaltic hydroxide (III) with conversion of cobalt (III) to cobalt (II). Then, the obtained solution is cleaned from impurities and metallic cobalt or its compounds are obtained. Cobaltic hydroxide (III) is diluted with the participation of recovered reduced forms of iron and/or copper salts in the range of oxidation-reduction potential of 300-700 mV relative to silver-chloride comparison electrode and pH 1-3, thus adjusting the temperature of the process by means of evaporation cooling. Recovery of reduced forms of iron and/or copper is performed in a separate unit using the reducer. At insufficient amount of copper and iron in raw material supplied to the process there performed is cleaning of leaching solution from copper by cementation and recirculation of cleaning product to the recovery stage of reduced forms of iron and/or copper.
EFFECT: improving the opening rate of initial raw material and simplifying the process.
12 cl, 2 dwg, 3 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR RECOVERY OF COBALT FROM MIDDLINGS CONTAINING COBALT OXIDES | 1996 |
|
RU2106417C1 |
METHOD OF SOLVING METAL HYDROXIDE AND REDUCTION OF METAL | 0 |
|
SU621768A1 |
0 |
|
SU434117A1 | |
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RU2080398C1 |
METHOD OF RECOVERING OSMIUM FOR ION-EXCHANGE RESIN | 1998 |
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PROCESSING METHOD OF COBALT-CONTAINING WASTES | 2012 |
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RU2489509C1 |
METHOD OF RECOVERY OF COBALT FROM COBALT-CONTAINING MATERIAL | 1998 |
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RU2127326C1 |
METHOD FOR PROCESSING FERROUS HYDRATE CAKES CONTAINING NICKEL AND COBALT | 0 |
|
SU996495A1 |
Authors
Dates
2012-03-10—Published
2010-08-20—Filed