METHOD OF PRODUCING HYDROGEN CYANIDE THROUGH CATALYTIC OXIDATION IN AMMONIA MEDIUM Russian patent published in 2012 - IPC B01J27/16 B01J27/185 B01J27/187 C01C3/02 

Abstract RU 2454277 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing hydrogen cyanide through catalytic oxidation of starting material in ammonia medium. The oxidation method is carried out in ammonia medium of alcoholic starting material such as methanol, or nitrile starting material such as propionitrile, or mixture thereof. To form hydrogen cyanide, modified Mn-P catalyst is used, having the following empirical formula: MnaPlAbOx, where A is one or more elements K, Ca, Mo, Zn, Fe or combination thereof; a varies from 1 to 1.5; b varies from 0.01 to 1.0 and x is the total number of oxygen atoms, which is determined from the oxidation state of present elements. The invention also includes a catalyst for oxidation in ammonia medium.

EFFECT: catalyst has high activity.

13 cl, 2 tbl, 5 ex

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RU 2 454 277 C2

Authors

Khramov Mikhail

Monikehl Vehleri

Korjabkina Natal'Ja

Dates

2012-06-27Published

2008-06-24Filed