FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing hydrogen cyanide through catalytic oxidation of starting material in ammonia medium. The oxidation method is carried out in ammonia medium of alcoholic starting material such as methanol, or nitrile starting material such as propionitrile, or mixture thereof. To form hydrogen cyanide, modified Mn-P catalyst is used, having the following empirical formula: MnaPlAbOx, where A is one or more elements K, Ca, Mo, Zn, Fe or combination thereof; a varies from 1 to 1.5; b varies from 0.01 to 1.0 and x is the total number of oxygen atoms, which is determined from the oxidation state of present elements. The invention also includes a catalyst for oxidation in ammonia medium.
EFFECT: catalyst has high activity.
13 cl, 2 tbl, 5 ex
Title |
Year |
Author |
Number |
CATALYST, A METHOD FOR PRODUCING A CATALYST AND A METHOD FOR PRODUCING ACRYLONITRILE |
2020 |
- Iitsuka, Chihiro
- Fukuzawa, Akiyoshi
|
RU2779498C1 |
METHOD FOR PRODUCING ACRYLONITRILE AND PREPARING HYDROGEN CYANIDE AND ACETONITRILE AS CO-PRODUCTS (VARIANTS) |
2001 |
- Godbol Sandzhaj P
- Sili Majkl Dzh
- Saresh Dev D
|
RU2264385C2 |
CATALYST AND METHOD FOR DIRECT CONVERSION OF SYNTHESIS GAS INTO LIGHT OLEFINS |
2017 |
- Bao, Xinhe
- Jiao, Feng
- Pan, Xiulian
- Ding, Minzheng
|
RU2727897C1 |
CRYSTALLINE BIS-AMMONIUM MOLYBDENUMATE OF TRANSITION METAL |
2016 |
- Miller, Stuart
- Collins, Laura
- Koster, Susan C.
|
RU2699797C1 |
METHOD OF SYNTHESIS CATALYSTS BASED ON VANADIUM ANTIMONATE USING SnO•xHO |
1998 |
- Brazdil Dzhejms Frehnk Ml.
- Bartek Dzhozef Piter
|
RU2195999C2 |
METHOD OF REMOVAL OF SULFUR-, NITROGEN- AND HALOGEN-CONTAINING ADMIXTURES, PRESENT IN SYNTHESIS-GAS |
2009 |
- Shish David
- Bude Nikolja
- Vigi Zhan-Kristof
- Lelia Mark-Antuan
- Djukre Oliv'E
|
RU2497575C2 |
IMPROVED METHOD FOR COMBINED PRODUCTION OF ACRYLONITRILE AND HYDROGEN CYANIDE |
2009 |
- Baskham Brent I.
- Stimek Richard T.
|
RU2494092C2 |
CARBOXYLIC ACID SYNTHESIS METHOD |
2006 |
- Bonne Did'E
- Petroff Sen-Arroma Romen
- Rigini Sebast'En
- Irelan Tan'Ja
- Simonato Zhan-P'Er
|
RU2398757C2 |
BIFUNCTIONAL CATALYST OF PARTIAL OXIDATION TO TURN PROPANE TO ACRYLIC ACID AND ITS PRODUCTION METHOD |
2012 |
- Khazin Polett
- Tennison Redzhinald
- Khakman Majkl
|
RU2621033C2 |
ALDEHYDES PRODUCTION PROCESS |
2016 |
- Holmberg Johan Bjorn Mattias
|
RU2712214C2 |