FIELD: process engineering.
SUBSTANCE: invention may be used for gas mix separation and fabrication of flow membrane catalysts in ultra- and microfiltration. Asymmetric flow module for membrane catalysis and/or gas separation at up to 1000°C comprises macroporous ceramic substrate and membrane. Said membrane is made by anodic oxidation of aluminium secured on substrate by thermosetting and has through pores perpendicular to membrane surface. Said pores feature diameter varying from 5 nm to 500 nm, preset architecture and dispersion of their diameters in aluminium oxide layer not exceeding 15%. Said module may be reclaimed in the case of organic substances by annealing in oxidative atmosphere. Preset architecture of pores is ensured by anodic oxidation carried out in several steps at different strains. Pore walls may be modified by applying metal catalytically active particles.
EFFECT: sufficient mechanical strength at pressure variations of up to 10 bar and stability after annealing at over 800°.
15 cl, 9 dwg, 1 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCTION OF FLEXIBLE NANOPOROUS COMPOSITE MEMBRANE WITH CELLULAR STRUCTURE OF ANODE METAL OXIDE OR ALLOY | 2012 |
|
RU2545887C2 |
ELASTIC ALUMINA NANO-MEMBRANE OBTAINING METHOD | 2017 |
|
RU2678055C2 |
METHOD FOR MANUFACTURE OF MEMBRANES | 0 |
|
SU1695970A1 |
METHOD OF MAKING ALUMINIUM OXIDE-BASED MEMBRANES | 2011 |
|
RU2474466C1 |
METHOD OF PRODUCING MEMBRANES WITH REGULAR NANOPORES FROM BARRIER-FILM METAL OXIDES | 2009 |
|
RU2405621C2 |
METHOD OF PRODUCING ANISOTROPIC NANOSTRUCTURES VIA FILTRATION OF COLLOIDAL SOLUTIONS THROUGH POROUS MEMBRANES WITH SINGLE-SIZE CHANNELS | 2009 |
|
RU2424043C1 |
METHOD FOR INCREASING SELECTIVITY OF NANOPOROUS MEMBRANES FOR EXTRACTION OF CONDENSED COMPONENTS FROM GAS MIXTURES AND MODIFIED MEMBRANE OBTAINED USING SAID METHOD | 2017 |
|
RU2696445C2 |
PROCESS TO MANUFACTURE POROUS ANODIC ALUMINA | 2006 |
|
RU2324015C1 |
PLANAR CONDENSER | 2016 |
|
RU2645731C1 |
COMPOSITE MEMBRANE FOR DRYING GAS MIXTURES BASED ON A MICROPOROUS POLYMER IN POROUS MATRIX | 2018 |
|
RU2720247C1 |
Authors
Dates
2012-07-10—Published
2009-10-23—Filed