FIELD: chemistry.
SUBSTANCE: invention relates to a method for liquid-phase oxidation of ethylbenzene to ethylbenzene hydroperoxide, where concentration of ethylbenzene hydroperoxide is kept below 20 wt % with respect to total weight of the reaction mixture and where styrene and/or a styrene derivative is added to ethylbenzene. Concentration of said styrene and/or styrene derivative can range from 0.01 to 5.0 wt %. The styrene derivative is a styrene derivative in which one or more unsubstituted carbon atoms of the styrene have an alkyl group and/or a halogen atom as a substitute. The invention also relates to a method of producing an alkylene oxide, preferably styrene and propyelene oxide.
EFFECT: improved method.
10 cl, 3 dwg, 1 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
ETHYLBENZENE HYDROPEROXIDE PRODUCTION PROCESS | 1998 |
|
RU2128647C1 |
METHOD OF PREPARING ETHYL BENZENE HYDROPEROXIDE | 1997 |
|
RU2117005C1 |
REACTOR APPARATUS FOR PRODUCING ETHYLBENZENE HYDROPEROXIDE | 1996 |
|
RU2116295C1 |
METHOD OF PRODUCING ETHYLBENZENE HYDROPEROXIDE | 1996 |
|
RU2114104C1 |
METHOD OF ALKYLEN OXIDE PRODUCTION | 2004 |
|
RU2354654C2 |
METHOD OF PRODUCING ETHYLBENZENE HYDROPEROXIDE | 2016 |
|
RU2633362C2 |
OXIRANE COMPOUNDS PREPARING | 2001 |
|
RU2282625C2 |
METHOD OF OBTAINING ETHYLBENZENE HYDROPEROXIDE | 1983 |
|
SU1220292A1 |
STYRENE-PROPYLENE OXIDE PRODUCTION PROCESS | 1999 |
|
RU2214385C2 |
METHOD OF PRODUCING STYRENE | 2016 |
|
RU2716265C2 |
Authors
Dates
2012-10-20—Published
2007-11-12—Filed