OLEFIN POLYMERISATION METHOD Russian patent published in 2012 - IPC C08F2/34 C08F10/00 C08F10/06 C08F4/654 

Abstract RU 2464282 C2

FIELD: chemistry.

SUBSTANCE: described is a method which involves gas-phase polymerisation of an olefin monomer in more than one polymerisation zone in the presence of a Ziegler-Natta catalyst containing a solid titanium-containing component deposited on magnesium, a cocatalyst - alkylaluminium and organosilane as an external electron donor. The method involves feeding the titanium-containing component and alkylaluminium into a first polymerisation zone and then feeding an additional amount of alkylaluminium into the next polymerisation zone without adding the titanium-containing component.

EFFECT: stepwise addition of the cocatalyst - alkylaluminium - increases output during the second step, which results in more uniform distribution of products between the two steps.

11 cl, 2 tbl, 18 ex

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RU 2 464 282 C2

Authors

Klarembo Mishel'

Striki Dzherom A.

Ehrnst Andreas B.

Dates

2012-10-20Published

2008-03-03Filed