METHOD OF PRODUCING ORGANOMETALLIC NICKEL (III) COMPLEXES Russian patent published in 2012 - IPC C07F15/04 

Abstract RU 2466135 C1

FIELD: chemistry.

SUBSTANCE: invention relates to organometallic chemistry and specifically to a method of producing organometallic nickel (III) complexes. The method is realised via oxidative bonding of an olefin to a cationic nickel (I) complex formed by oxidising bis(cyclooctadiene-1,5)nickel with boron trifluoride etherate. Formation of catalytically active organometallic nickel (III) complexes is carried out in molar ratio B:Ni=2:1.

EFFECT: invention considerably simplifies obtaining organometallic nickel (III) complexes which exhibit high catalytic activity with respect to olefins.

2 dwg, 5 ex

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RU 2 466 135 C1

Authors

Krajkivskij Petr Bogdanovich

Saraev Vitalij Vasil'Evich

Bocharova Viktorija Vladimirovna

Matveev Dmitrij Aleksandrovich

Dates

2012-11-10Published

2011-02-28Filed