FIELD: chemistry.
SUBSTANCE: invention relates to organometallic chemistry and specifically to a method of producing organometallic nickel (III) complexes. The method is realised via oxidative bonding of an olefin to a cationic nickel (I) complex formed by oxidising bis(cyclooctadiene-1,5)nickel with boron trifluoride etherate. Formation of catalytically active organometallic nickel (III) complexes is carried out in molar ratio B:Ni=2:1.
EFFECT: invention considerably simplifies obtaining organometallic nickel (III) complexes which exhibit high catalytic activity with respect to olefins.
2 dwg, 5 ex
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Authors
Dates
2012-11-10—Published
2011-02-28—Filed