FIELD: chemistry.
SUBSTANCE: invention relates to obtaining n-cemene hydroperoxide, which can be used for combined production of cresol and acetone. In accordance with invention claimed is method of obtaining n-cymene hydroperoxide by liquid-phase oxidation of n-cymene with air oxygen at atmospheric pressure, temperature of the process 80-110°C, for 1-3 hours, in presence of N-hydroxyphthalimide as catalyst in amount 1-5 wt %, until content of n-cymene hydroperoxyde is 25-28%.
EFFECT: catalyst excludes application of initiator and alkaline additives, which simplifies the process considerably; high rate of n-cymene oxidation is achieved.
1 cl, 3 ex
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Authors
Dates
2012-11-20—Published
2011-04-01—Filed