FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing methanol by bringing a feed stream rich in hydrogen and carbon monoxide in a reactor into contact with a methanol synthesis catalyst to obtain a process stream, followed by cooling thereof, condensation and separation into a gas phase and a liquid phase with crude methanol. The feed stream used is cleaned gas which is obtained by direct-flow gasification of wood processing wastes. The feed stream is enriched with hydrogen by controlled electrolysis of recycled water before bringing the feed stream into contact with a catalyst containing the following, wt %: copper oxide 62, zinc oxide 31, aluminium oxide 7. The feed stream is compressed to pressure of 4.5-5 MPa and then divided into two streams. One stream is fed into the reactor onto the catalyst for contacting through a heat exchanger which simultaneously cools the process stream. The other stream is fed directed onto the catalyst for contacting and reaction temperature is maintained at 250-270°C. After final cooling of the process stream in the still residue of the distillation apparatus, it is separated by throttling into a gas phase and a liquid phase. After separation, the gas phase is divided into two streams. One stream is fed for oxidation into a direct-flow gasifier and the other is mixed with the feed stream before compression.
EFFECT: invention enables to obtain the desired product via a wasteless method using one readily available catalyst.
1 dwg
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Authors
Dates
2013-04-10—Published
2012-02-28—Filed