FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing a N,S-cyclo-containing chitosan derivative. Described is a method of producing a chitosan-based N,S-cyclo-containing polymer (I) which contains in the macrochain 1-oxa-6-thia-4,8-diazocycloundecane fragments: I, by reacting chitosan with formaldehyde and a S-containing compound, characterised by that the S-containing compound used is hydrogen sulphide, the formaldehyde solution is pre-saturated with H2S and the reaction is carried out with molar ratio chitosan: formaldehyde: hydrogen sulphide of 1:2:1, at temperature of 0-60°C in a chloride medium for 24 hours.
EFFECT: obtaining modified chitosan which exhibits properties of a highly efficient heavy metal sorbent for waste water treatment, an extractant for separating rare, noble and precious metals and a complexing agent for biological molecules.
1 tbl, 3 ex
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METHOD OF PRODUCING N-(1,3,5-DITHIAZINAN-5-YL)-THIOUREA | 2009 |
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HYDROGEN SULPHIDE RELEASING POLYMER COMPOUNDS | 2017 |
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RU2768716C2 |
METHOD OF PRODUCING 1,3,5-THIADIAZINAN-4-(THI)ONES | 2010 |
|
RU2447067C1 |
METHOD OF OBTAINING 3,3'-(3,6-DIOXAOCTANE-1,8-DIYL)BIS-1,5,3-DITHIAZEPINANE AND ITS APPLICATION AS AGENT WITH FUNGICIDAL ACTIVITY | 2013 |
|
RU2547267C2 |
Authors
Dates
2013-04-10—Published
2010-06-02—Filed