FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing curing agents for epoxy resins for making large articles, anticorrosion coatings and other purposes. The curing agents are obtained by mixing a eutectic mixture of aromatic amines with a product of reacting an acid of general formula R2R COOH, where R is an aliphatic, cycloaliphatic or aromatic hydrocarbon moiety, R2 is a substitute -Cl, -F, -NH2, -NH-, -OH, -CH=CH-, -CH=CH2 (A) with a di- or polyamine of an aliphatic, cycloaliphatic or aromatic type, (B) and a polyatomic alcohol with containing 2-6 hyroxyls per molecule, (C) with ratio A:B:C from 70:29:1 to 20:70:10 by mixing in a medium of an ether of a di- or tricarboxylic acid and a monoatomic alcohol at temperature of 20-80°C for 10-120 minutes, with the ratio of the reaction product to the eutectic mixture of aromatic amines from 5:95 to 95:5.
EFFECT: invention enables to obtain curing agents which enable to reduce the exothermic effect when curing large-sized articles and increase strength of the obtained polymers during cavitational action of water.
2 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
EPOXIDE COMPOSITION | 2011 |
|
RU2478669C1 |
POLYMER COMPOSITION | 2011 |
|
RU2478671C1 |
METHOD OF PRODUCING CURING AGENTS OF EPOXY RESINS | 2011 |
|
RU2476452C1 |
METHOD OF PREPARING COLD-HARDENING EPOXIDE RESIN HARDENERS | 2001 |
|
RU2207349C2 |
POLYMER COMPOSITION | 2011 |
|
RU2506291C2 |
METHOD OF REINFORCING POWER CONSTRUCTIONS | 2011 |
|
RU2516185C2 |
METHOD FOR PREPARING EPOXY RESIN HARDENING AGENT | 2003 |
|
RU2267501C2 |
POLYMER COMPOSITION | 2011 |
|
RU2507227C2 |
EPOXY COMPOSITE | 2001 |
|
RU2186801C1 |
POLYMER COMPOSITION | 2011 |
|
RU2528681C2 |
Authors
Dates
2013-07-27—Published
2011-08-03—Filed