FIELD: chemistry.
SUBSTANCE: present invention relates to production of polymer compositions based on epoxy resins and modified amine curing agents, intended for producing high-strength composite materials with high resistance to thermal deformation. Described is a polymer composition based on epoxy resin, active epoxy diluents and nitrogen-containing curing agents intended for producing high-strength composite materials with high resistance to thermal deformation, characterised by that the curing agent is a product of reaction of an amine component with monocarboxylic acids, using as the amine component a mixture consisting of a primary aromatic amine or a mixture of aromatic amines (A), a secondary aliphatic amino alcohol (B) and a tertiary aliphatic amino alcohol (C) in weight ratio A:B:C from 98:0.2:1.8 to 80:5:15, and a monocarboxylic acid (D) is added in form of a 25-80% solution to the monoatomic aliphatic or aromatic alcohol, or ester thereof with a mono- or dicarboxylic acid, in ratio (A+B+C):D from 90:10 to 60:40 per 100% acid, followed by reaction by mixing in a reactor at temperature ranging from 50 to 130°C for 20 to 120 minutes and mixer speed of 100 to 3000 rpm, and additionally contains a thickener, a pigment or a dye, wherein the composition contains the following in pts.wt: epoxy resin - 100, active epoxy diluent - 5-130, curing agent - 15-110, thickener - 5-50, pigment and dye - 0.5-25.
EFFECT: obtaining compositions having a long life during processing, having in a cured state high resistance to thermal deformation and improved dielectric properties.
2 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF REINFORCING POWER CONSTRUCTIONS | 2011 |
|
RU2516185C2 |
METHOD OF PRODUCING CURING AGENTS OF EPOXY RESINS | 2011 |
|
RU2476452C1 |
METHOD OF PREPARING COLD-HARDENING EPOXIDE RESIN HARDENERS | 2001 |
|
RU2207349C2 |
EPOXY COMPOSITE | 2001 |
|
RU2186801C1 |
EPOXIDE COMPOSITION | 2011 |
|
RU2478669C1 |
POLYMER COMPOSITION | 2011 |
|
RU2528681C2 |
METHOD OF PRODUCING CURING AGENTS OF EPOXY RESINS | 2011 |
|
RU2488611C2 |
METHOD OF PRODUCING EPOXY RESIN CURING AGENTS | 2011 |
|
RU2507226C2 |
EPOXIDE COMPOSITION | 2003 |
|
RU2283333C2 |
POLYMER COMPOSITION | 2001 |
|
RU2239643C2 |
Authors
Dates
2014-02-10—Published
2011-12-28—Filed