FIELD: chemistry.
SUBSTANCE: invention relates to catalysts of olefin hydroamination, their obtaining and application. Claimed is lithium-ligated hydroamination catalyst, which contains boron-beta-zeolites, molar ratio of boron atoms to lithium atoms constituting from 5:1 to 50:1. Also described is method of obtaining amines by converting ammonium or primary, respectively secondary amines with olefins at higher temperatures and pressure in presence of said hydroamination catalyst. Claimed is method of obtaining raw material for rubber industry: vulcanisation accelerators, methods of plant protection or pharmaceutical preparations with application of tert-butyl amine preliminarily obtained by method described above.
EFFECT: increased amine output.
10 cl, 1 tbl, 13 ex
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Authors
Dates
2013-08-20—Published
2010-04-19—Filed