FIELD: chemistry.
SUBSTANCE: present invention relates to methods and systems for processing triglyceride-containing, biologically-derived oils to obtain base oils and transportation fuels. The method comprises the following steps: a) processing a triglyceride-containing vegetable oil to effect oligomerisation of unsaturated fatty acid components contained therein so as to obtain an oligomerised mixture; b) isomerising the oligomerised mixture over an isomerisation catalyst to obtain an isomerised mixture, wherein the isomerised mixture comprises a base oil component and a diesel fuel component; c) removing water from the isomerised mixture to obtain a dry isomerised mixture, wherein the dry isomerised mixture comprises at least 10 wt % alkanes having 30 or more carbon atoms; d) separating the dry isomerised mixture into a lower boiling fraction from which diesel fuel is subsequently derived, and a higher boiling fraction; and e) subsequently further isomerising at least a portion of the higher boiling fraction to obtain a base oil. A system for producing base oil and diesel fuel is also disclosed.
EFFECT: providing multiple product streams of given quality.
15 cl, 4 dwg, 1 ex
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Authors
Dates
2013-10-10—Published
2009-07-22—Filed