FIELD: chemistry.
SUBSTANCE: method involves catalytic telomerisation of butadiene with diethylamine in the presence of a catalyst based on cationic complexes of palladium (II) of general formula [(acac)Pd(L)2]BF4 (where acac is an acetylacetonate ligand, L=PPh3, P'Pr3, P"Bu3 P(p-Tol)3 or (L)2=diphosphine ligands, selected from bis(diphenylphosphino)methane(dppm), bis(diphenylphosphino)propane(dppp), bis(diphenylphosphino)butane(dppb), bis(diphenylphosphino)ferrocene(dppf)). The process is carried out in a substrate medium, specifically diethylamine and butadiene, at temperature of 50-90°C. The method enables to obtain N,N-diethylocta-2,7-diene-1-amine with selectivity of 99.9% from the overall mixture of reaction products with high process output which reaches 4180 g of product per 1 g Pd. The catalysts used are more readily available compared to those previously used for the process.
EFFECT: improved method.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING CATIONIC COMPLEXES OF PALLADIUM WITH BIDENTATE ORGANOPHOSPHORUS LIGANDS | 2011 |
|
RU2475492C1 |
| METHOD OF PRODUCING CATIONIC COMPLEXES OF PALLADIUM WITH PHOSPHINE LIGANDS | 2017 |
|
RU2636741C1 |
| METHOD OF PREPARING N,N-DIETHYL-N- OCTA-2,7-DIEN-1- YLAMINE | 1992 |
|
RU2111956C1 |
| METHOD OF OBTAINING DIFFERENT-LIGAND CATIONIC COMPLEXES OF PALLADIUM | 2009 |
|
RU2423373C1 |
| METHOD OF OBTAINING CATION COMPLEXES OF PALLADIUM | 2006 |
|
RU2329269C2 |
| METHOD OF PRODUCING PALLADIUM CATION COMPLEXES WITH TERTIARY AMINES | 2017 |
|
RU2636742C1 |
| METHOD OF OBTAINING CATIONIC PALLADIUM COMPLEXES | 2011 |
|
RU2466134C1 |
| METHOD OF ADDITIVE POLYMERIZATION OF NORBORNEN AND ITS DERIVATIVES | 2015 |
|
RU2626745C2 |
| METHOD OF PRODUCING (ACETYLACETONATO-κ-O,O')(BIS-ACETONITRILE)PALLADIUM TETRAFLUOROBORATE | 2011 |
|
RU2456295C1 |
| METHOD OF TELOMERIZATION OF DIENE WITH CONJUGATED DOUBLE BONDS, CATALYST AND BIDENTATE LIGAND USED IN INDICATED METHOD | 2002 |
|
RU2318790C2 |
