FIELD: chemistry.
SUBSTANCE: method of producing polymer nanocomposites in form of thin films for superdense information recording involves producing a precursor consisting of polyvinyl alcohol, water and a mixture of water-soluble salts of ferric and ferrous iron, followed by treatment with at least one water-soluble dialdehyde at pH 0-3 in the presence of an acid as an acidifying agent, obtaining a thin film on a dielectric nonmagnetic substrate depositing the precursor on a substrate rotating on a centrifuge to form a gel film, treating the obtained gel film with an alkali, the alkali being added in an amount allows complete alkaline hydrolysis of the mixture of iron salts to form a mixture of magnetite or maghemite. The obtained gel film is treated with the alkali in ammonia vapour which is formed from aqueous ammonia solution (NH4OH) or hydrazine hydrate (N2H4·H2O) for 5.0-15.0 hours.
EFFECT: reduced particle size dispersion of magnetite and maghemite nanoparticles, obtaining a nanocomposite with a uniform structure, the obtained structure can be used as storage medium for superdense magnetic information recording.
2 dwg, 1 ex
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Authors
Dates
2014-06-20—Published
2012-12-28—Filed