FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing n-(N-glucosylidene)aminobenzoic acid of general formula: (where R is a straight or branched aliphatic radical with 1-9 carbon atoms), which can be used as sunscreen agents in cosmetics and as biologically active substances in medicine. The method includes hydrogenation of corresponding esters of n-nitrobenzoic acid and condensation of the obtained amines with glucose in one reactor at 20-55°C (preferably 45°C) in the presence of a AB-17-8- Pd catalyst (CH3COO- form).
EFFECT: invention enables to obtain end products using a simple method.
1 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
3-(4-CARBETHOXY)PHENYLIMINO-2-OXOINDOLINE IMPROVING RESISTANCE OF ORGANISM TO REPEATED SKULL AND BRAIN INJURY | 1979 |
|
SU749063A1 |
METHOD FOR PREPARING 1-HYDROXY-5-OXO-5H-PYRIDO-(3,2-A)-PHENOXAZIN-3-CARBOXYLIC ACID ESTERS | 0 |
|
SU1628858A3 |
METHOD OF PREPARING CYANACRYLIC ACID ESTERS | 0 |
|
SU726086A1 |
DERIVATIVES OF THIAZOLIDINEDIONE, THEIR SYNTHESIS AND PHARMACEUTICAL COMPOSITION | 1993 |
|
RU2129553C1 |
ESTERS OF ACYLSULFONAMIDO- AND SULFONAMIDOPYRIDINE-2-CARBOXYLIC ACID, PHARMACEUTICAL COMPOSITION CONTAINING THEREOF AND A METHOD OF ITS PREPARING | 1993 |
|
RU2117660C1 |
METHOD OF PRODUCING (D,1)-2,6,11-/DIHYDRODIBENZO-THIEPINE-11-ONE-3-/YL-PROPYONIC ACIDS, SALTS OR ESTERS THEREOF | 0 |
|
SU670223A3 |
PROCESS FOR PREPARING N,N-SUBSTITUTED DITHIOCARBAMINIC ACID ESTERS, 3,5-DIALKYL(CYCLOALKYL, ARALKYL, OR ARYL)-4-OXYBENZYL ALCOHOLS | 1992 |
|
RU2081110C1 |
METHOD OF PRODUCING ESTERS OF N-ACYL-N-ARYL-ALHA-AMINO ACIDS | 0 |
|
SU1447814A1 |
N-PHENYL-2-PYRIMIDINE DERIVATIVES | 2003 |
|
RU2370493C2 |
N-(BIPHENYLMETHYL)AMINOBENZOIC ACID ESTERS AND METHOD OF THEIR SYNTHESIS | 1995 |
|
RU2144022C1 |
Authors
Dates
2014-09-27—Published
2012-12-14—Filed