METHOD OF PRODUCING 1-(3-PHENOXYPHENYL)BUTANE-1,3-DIONE Russian patent published in 2014 - IPC C07C45/72 C07C49/84 

Abstract RU 2529029 C1

FIELD: chemistry.

SUBSTANCE: method includes reacting a 3-phenoxybenzoic acid derivative with a sodium enolate of acetoacetic ester, wherein the 3-phenoxybenzoic acid derivative used is 3-phenoxybenzoic acid acyl chloride, and the reaction is carried out in molar ratio of reactants of 1:1, in a medium of absolute diethyl ether at room temperature for 3-5 hours, to form ethyl 3-oxo-2-(3-phenoxybenzoyl)butanoate, subsequent hydrolysis thereof in excess water at 100°C for 2 hours.

EFFECT: method reduces the number of synthesis steps, simplifies implementation of the process and enables to obtain an end product with high output.

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RU 2 529 029 C1

Authors

Popov Jurij Vasil'Evich

Korchagina Tat'Jana Konstantinovna

Kalmykova Galina Viktorovna

Losevskaja Lilija Aleksandrovna

Dates

2014-09-27Published

2013-05-13Filed