METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES Russian patent published in 2014 - IPC C07D285/36 

Abstract RU 2536149 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method of obtaining 3-aryl-1,5,3-dithiazepanes of general formula where R = H (a), m-CH3 (b), p-CH3 (c), o-OCH3 (d), m-OCH3 (e), p-OCH3 (f), o-NO2 (g), m-NO2 (h), p-NO2 (i), characterised by the fact that N1,N1,N6,N6-tetramethyl-2,5-dithiahexane-1,6-diamine is subjected to interaction with arylamine (aryl = phenyl, m- and p-methylphenyl, o-, m- and p-methoxyphenyl, o-, m- and p-nitrophenyl) in the presence of a catalyst FeCl3·6H2O in a molar ratio N1,N1,N6,N6-tetramethyl-2,5-dithiahexane-1,6-diamine: arylamine:FeCl3·6H2O=10:10:(0.3-0.7) at a temperature of ~60°C and atmospheric pressure in chloroform as a solvent for 50-80 minutes.

EFFECT: elaborated is the method of obtaining derivatives of 3-aryl-1,5,3-dithiazepanes, which can be applied as antibacterial, antifungal and antiviral agents, as biologically active complexants, selective sorbents and extractants of precious metals, special reagents for the suppression of bacteria activity in various technical media.

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RU 2 536 149 C2

Authors

Dzhemilev Usein Memetovich

Ibragimov Askhat Gabdrakhmanovich

Khalilov Leonard Mukhibovich

Makhmudijarova Natal'Ja Nail'Evna

Prokof'Ev Kirill Igorevich

Mudarisova Lilija Vazilevna

Dates

2014-12-20Published

2013-01-28Filed