FIELD: chemistry.
SUBSTANCE: invention relates to organic chemistry and a method of producing 3,3'-[bis-(1,4-phenylene)]bis-1,3,5-dithiazinanes of formula (1): 
wherein diphenylenediamine (diaminodiphenylmethane, diaminodiphenyl oxide) reacts with N-tert-butyl-1,3,5-dithiazinane in the presence of a Sm(NO3)3·6H2O catalyst in an argon atmosphere in molar ratio diphenylenediamine: N-tert-butyl-1,3,5-dithiazinane:Sm(NO3)3·6H2O=1:2:(0.03-0.07) at about 20°C in an ethanol-chloroform solvent system (1:1, by volume) for 2.5-3.5 hours.
EFFECT: method of obtaining novel compounds which can be used as antimicrobial and antifungual agents, selective sorbents and extractants of precious metals, special reagents for inhibiting bacterial activity in different process media.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR SELECTIVE PRODUCTION OF 3,3'-[BIS-(1,4-PHENYLENE)]BIS-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2529506C2 |
| METHOD OF SELECTIVE OBTAINING 3,3'-[METHYLENEBIS(1,4-PHENYLENE)]-, 3,3'-[OXYBIS(1,4-PHENYLENE)]- AND 3,3'-(3,3'-DIMETHOXYBIPHENYL-4, 4'-DIYL)-BIS-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2518485C2 |
| METHOD OF OBTAINING 3,3'-(1,2-PHENYLENE)-BIS-1,5,3-DITHIAZEPINANE AND 3,3,-[METHYLENE-BIS-(1,4-PHENYLENE)]-BIS-1,5,3- DITHIAZEPINANE | 2011 |
|
RU2467006C1 |
| METHOD OF OBTAINING N,N'-BIS-(3-MERCAPTOPHENYL)TETRATHIADIAZACYCLOALKANES | 2013 |
|
RU2538595C1 |
| METHOD OF OBTAINING 3, 3'-[OXA(THIA)ALKANE-alpha, omega-DIYL]-BIS-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2518482C2 |
| METHOD OF OBTAINING 3,3'-(3,6-DIOXAOCTANE-1,8-DIYL)BIS-1,5,3-DITHIAZEPINANE AND ITS APPLICATION AS AGENT WITH FUNGICIDAL ACTIVITY | 2013 |
|
RU2547267C2 |
| METHOD OF PRODUCING α,ω -BIS-(1,5,3-DITHIAZEPINAN-3-YL)ALKANES | 2011 |
|
RU2478634C2 |
| METHOD FOR PREPARING (1,5,3-DITIAZEPINAN-3-YL)(THIO)PHENOLS | 2011 |
|
RU2478623C2 |
| METHOD OF PRODUCING N,N-BIS-[(1,5,3-DITHIAZEPAN-3-YL)ALKYL]AMINES | 2014 |
|
RU2591196C2 |
| METHOD OF PRODUCING OF BIS-(1,5,3-DITHIAZEPAN-3-IL)CYCLOHEXANES | 2014 |
|
RU2574069C1 |
