FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 1,3,5-trihydroxyadamantane. The method includes oxidising 1-adamantanol with molecular oxygen in the presence of N-hydroxyphthalimide in molar ratio of 1:0.05-0.2 with respect to 1-adamantanol, cobalt (II) acetylacetonate in molar ratio of 1:0.0025-0.02 with respect to 1-adamantanol and manganese dioxide in molar ratio of 1:0.01-0.1 with respect to 1-adamantanol at 50-118°C in a medium of glacial acetic acid for 10-40 hours.
EFFECT: method enables to obtain an end product with high output using readily available material using a simple method.
13 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 7-ETHYL-1,3,5-TRIHYDROXYADAMANTANE | 2017 |
|
RU2708633C2 |
| METHOD OF PREPARING IMIDAZO (2,5-A)-(1,4)-DIAZEPIN COMPOUNDS OR THEIR PHARMECETICALLY ADOPTED SALTS | 0 |
|
SU814278A3 |
| CATALYTIC ALKANE OXIDATION PROCESS | 2002 |
|
RU2284986C2 |
| CATALYST FOR OXIDATION OF C1-C4 ALCOHOLS TO ESTERS | 0 |
|
SU655286A3 |
| METHOD OF PRODUCING ADAMANTYL-CONTAINING β-DICARBONYL COMPOUNDS | 2012 |
|
RU2496766C1 |
| THIOXANTHENONE COMPOUNDS AND PHARMACEUTICAL COMPOSITIONS SHOWING ANTITUMOR ACTIVITY | 1994 |
|
RU2138495C1 |
| METHOD FOR PRODUCTION OF 4,17(20)-Z-PREGNADIENE-3,16-DIONE, METHOD FOR COMPOUND PRODUCTION | 2004 |
|
RU2309159C2 |
| METHOD OF PREPARING DERIVATIVES OF IMIDAZO-/1,5-A/-(1,4)-DIAZEPINE OR THEIR SALTS | 0 |
|
SU730308A3 |
| METHOD OF OBTAINING HYDROCHLORIDES OF ADAMANTANE AMINES | 2013 |
|
RU2541545C2 |
| METHOD OF PREPARING HEXAHYDROBENZPYRANOXATENONES | 0 |
|
SU793395A3 |
