FIELD: chemistry.
SUBSTANCE: invention relates to organic chemistry and specifically to a method of producing adamantane derivatives of β-diketones, which are intermediate products for organic synthesis and potential ligands for metal ions. The method of producing adamantyl-containing β-dicarbonyl compounds from 1-adamantanol and β-dicarbonyl compounds is carried out in the medium of an organic solvent with Lewis acid catalysis, where the Lewis acid used is indium triflate in amount of 5 mol %, and the organic solvent used is 1,2-dichloroethane; the reaction is carried out while heating at boiling point until exhaustion of starting components, which are taken in equimolar amounts.
EFFECT: environmentally safe method of producing a range of adamantyl-containing β-dicarbonyl compounds using commercially available starting compounds with good output of the end product.
5 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
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|
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| METHOD OF PRODUCING 1-ADAMANTYL FERROCENE | 2018 |
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