FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing a sorbent for selective extraction of scandium ions. The method includes a step for acylation of a styrene and divinylbenzene copolymer with acetylchloride in dichloroethane solution in the presence of anhydrous aluminium chloride, washing and drying, a step for phosphorylation of the acylation product with phosphorus trichloride, a step for hydrolysis with ice water and final washing of the end product. The starting copolymer used is a macroporous copolymer of styrene and divinylbenzene. Acylation is carried out at the boiling point of the acetyl chloride solution. Phosphorylation is carried out by first holding the reaction mass at room temperature and then adding glacial acetic acid and further holding the reaction mass while stirring.
EFFECT: obtaining a complexing sorbent which is highly selective to scandium and improved process.
4 cl, 1 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING FIBROUS SORBENT FOR EXTRACTING SCANDIUM | 2015 |
|
RU2607215C1 |
SOLID EXTRAGENT WITH HIGH DYNAMIC EXCHANGE CAPACITY FOR SCANDIUM EXTRACTION AND THE METHOD OF ITS PREPARATION | 2017 |
|
RU2650410C1 |
0 |
|
SU280839A1 | |
PROCESS FOR PRODUCING PHOSPHORUS-CONTAINING SORBENTS | 0 |
|
SU1063804A1 |
0 |
|
SU531815A1 | |
METHOD FOR PRODUCING COMPLEX-FORMING SORBENT FOR SELECTIVE RECOVERY OF INDIUM | 2012 |
|
RU2560361C2 |
TECHNIQUE OF PRODUCTION OF IONITE | 0 |
|
SU1835403A1 |
0 |
|
SU537086A1 | |
0 |
|
SU196310A1 | |
ANION-EXCHANGE SORBENT FOR SIMULTANEOUS ION CHROMATOGRAPHIC DETERMINATION OF POLARISABLE AND NON-POLARISABLE INORGANIC ANIONS AND METHOD FOR PRODUCTION THEREOF | 2012 |
|
RU2496571C1 |
Authors
Dates
2014-10-27—Published
2013-04-26—Filed