METHOD OF PRODUCING SORBENT FOR SELECTIVE EXTRACTION OF SCANDIUM IONS Russian patent published in 2014 - IPC B01J20/30 C08F8/10 C08F8/40 C08F212/08 C08F212/36 

Abstract RU 2531916 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing a sorbent for selective extraction of scandium ions. The method includes a step for acylation of a styrene and divinylbenzene copolymer with acetylchloride in dichloroethane solution in the presence of anhydrous aluminium chloride, washing and drying, a step for phosphorylation of the acylation product with phosphorus trichloride, a step for hydrolysis with ice water and final washing of the end product. The starting copolymer used is a macroporous copolymer of styrene and divinylbenzene. Acylation is carried out at the boiling point of the acetyl chloride solution. Phosphorylation is carried out by first holding the reaction mass at room temperature and then adding glacial acetic acid and further holding the reaction mass while stirring.

EFFECT: obtaining a complexing sorbent which is highly selective to scandium and improved process.

4 cl, 1 tbl, 2 ex

Similar patents RU2531916C1

Title Year Author Number
METHOD OF PRODUCING FIBROUS SORBENT FOR EXTRACTING SCANDIUM 2015
  • Grachek Valentina Ivanovna
  • Sokolova Yuliya Vasilevna
  • Pirozhenko Kirill Yurevich
  • Polikarpov Aleksandr Petrovich
RU2607215C1
SOLID EXTRAGENT WITH HIGH DYNAMIC EXCHANGE CAPACITY FOR SCANDIUM EXTRACTION AND THE METHOD OF ITS PREPARATION 2017
  • Kondrutskij Dmitrij Alekseevich
  • Kirillov Evgenij Vladimirovich
  • Rychkov Vladimir Nikolaevich
  • Kirillov Sergej Vladimirovich
  • Bunkov Grigorij Mikhajlovich
  • Vostrov Evgenij Sergeevich
  • Tretyakov Vitalij Aleksandrovich
  • Gadzhiev Gadzhi Rabadanovich
  • Poponin Nikolaj Anatolevich
  • Smyshlyaev Denis Valerevich
RU2650410C1
0
SU280839A1
PROCESS FOR PRODUCING PHOSPHORUS-CONTAINING SORBENTS 0
  • Zitsmanis Andris Khugovich
  • Vorobeva Valentina Karpovna
  • Lejkin Yurij Alekseevich
SU1063804A1
0
  • Balakin Vyacheslav Mikhajlovich
  • Tesler Aleksandr Germanovich
  • Afanaseva Tatyana Mikhajlovna
SU531815A1
METHOD FOR PRODUCING COMPLEX-FORMING SORBENT FOR SELECTIVE RECOVERY OF INDIUM 2012
  • Kondrutskij Dmitrij Alekseevich
  • Gadzhiev Gadzhi Rabadanovich
  • Bobrov Aleksandr Faddeevich
  • Nesterov Aleksej Gennad'Evich
  • Tret'Jakov Vitalij Aleksandrovich
RU2560361C2
TECHNIQUE OF PRODUCTION OF IONITE 0
  • Zhukova Nellya Garifovna
  • Polyakova Olga Pavlovna
  • Akulina Svetlana Aleksandrovna
  • Rodionov Vladimir Vasilevich
  • Zharova Evgeniya Vasilevna
  • Baskakov Anatolij Nikolaevich
  • Meshin Vitalij Veniaminovich
  • Frolov Aleksandr Ivanovich
  • Bogdanchikov Evgenij Viktorovich
  • Skvortsov Aleksandr Yurevich
  • Vodolazov Lev Ivanovich
SU1835403A1
0
  • Makarova Serafima Borisovna
  • Kitari-Oglu Vladimir Georgievich
  • Shabanova Nina Viktorovna
  • Vitols Oyars Ansovich
  • Smirnov Anatolij Vasilevich
SU537086A1
0
SU196310A1
ANION-EXCHANGE SORBENT FOR SIMULTANEOUS ION CHROMATOGRAPHIC DETERMINATION OF POLARISABLE AND NON-POLARISABLE INORGANIC ANIONS AND METHOD FOR PRODUCTION THEREOF 2012
  • Zatirakha Aleksandra Valer'Evna
  • Smolenkov Aleksandr Dmitrievich
  • Shpigun Oleg Alekseevich
  • Popik Mikhail Vasil'Evich
RU2496571C1

RU 2 531 916 C1

Authors

Tret'Jakov Vitalij Aleksandrovich

Kondrutskij Dmitrij Alekseevich

Bobrov Aleksandr Faddeevich

Gadzhiev Gadzhi Rabadanovich

Nesterov Aleksej Gennad'Evich

Dates

2014-10-27Published

2013-04-26Filed