FIELD: oil and gas industry.
SUBSTANCE: invention is referred to the area of petroleum chemistry and may be used for synthesis of methanol, dimethyl ether, hydrocarbons according to Fischer-Tropsch method. Methane-containing raw material is subjected to oxidative conversion at temperature of 650-1100°C in the riser. Miscrospheric or shredded catalyst based on metal oxides capable of multiple reduction-oxidative transfers is used as the oxidizer. Regenerated catalyst is recovered by its oxidation in the regenerator and addition to the riser in the bottom-up flow of methane-containing raw material; the riser operates in a through flow mode and duration of the raw material stay in the reaction area is 0.1-10 s. The regenerated catalyst exiting from the riser is separated from the product of synthetic gas and delivered to the regenerator. Catalyst regeneration is performed in fluidized, forced fluidized or semi-through flow by oxidation with oxygen-containing agent. The produced synthetic gas has H2/CO ratio within the range of 7.5-2.5.
EFFECT: improvement of the product area efficiency, potential usage of hydrocarbon raw material containing carbon dioxide at reduced explosion and fire hazard and at low energy consumption.
5 cl, 3 tbl, 13 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| CATALYST, METHOD FOR PRODUCTION THEREOF AND METHOD OF PRODUCING SYNTHESIS GAS | 2013 | 
 | RU2547845C1 | 
| METHOD OF PRODUCING SYNTHESIS GAS | 2013 | 
 | RU2556941C2 | 
| OBTAINING AROMATIC HYDROCARBON FROM METHANE | 2008 | 
 | RU2460581C2 | 
| METHANE AROMATISATION CATALYST, METHOD FOR PRODUCTION THEREOF AND METHOD OF CONVERTING METHANE TO PRODUCE AROMATIC HYDROCARBONS | 2015 | 
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 | RU2491118C1 | 
| PROCESS FOR PREPARING OLEFINIC HYDROCARBONS | 1997 | 
 | RU2127242C1 | 
| CATALYST AND METHOD OF PRODUCING SYNTHESIS GAS FROM METHANE AND ITS USE | 2015 | 
 | RU2621689C1 | 
| INTEGRATION OF OXIDATIVE COMBINATION INTO METHANE PLANTS | 2018 | 
 | RU2764097C2 | 
| METHOD OF PREPARING CATALYST FOR OXIDATIVE CONDENSATION OF METHANE, CATALYST PREPARED USING SAID METHOD, AND METHOD FOR OXIDATIVE CONDENSATION OF METHANE USING OBTAINED CATALYST | 2013 | 
 | RU2515497C1 | 
| CATALYTIC CONVERSION OF DISULPHIDE OIL IN PRESENCE OF WATER | 2016 | 
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Authors
Dates
2014-11-20—Published
2012-08-29—Filed