FIELD: physics, atomic power.
SUBSTANCE: invention relates to methods of processing uranium-containing solutions obtained from dissolving fluorination cinder when producing uranium hexafluoride. The method includes dissolving cinder in nitric acid solution, extracting uranium from the fluorine-containing nitric acid solution via reduction thereof with hydrazine on a platinum catalyst, with constant removal of uranium tetrafluoride precipitate from the catalyst surface, separating the catalyst from the nitric acid solution and the uranium tetrafluoride precipitate, providing an equimolar radio of fluoride ions to uranium (IV) in the obtained solution and separating the uranium tetrafluoride precipitate from the nitric acid solution, wherein the nitric acid solution is reused to resolve fluorination cinder with preliminary fortification with nitric acid.
EFFECT: invention provides a high degree of reducing uranium and reduces the amount of nitrate- and fluorine-containing wastes.
3 cl, 2 dwg
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Authors
Dates
2015-01-10—Published
2013-07-23—Filed