FIELD: chemistry.
SUBSTANCE: invention relates to field of organic chemistry, in particular to method of obtaining 1-azido-2-ethyl-1,2-dihydro(C60-Ih)[5,6]fullerene of formula (1) 
, which can be applied as donor-acceptor system, imitating photosynthesis, which transform sunlight into electric energy, generating active forms of oxygen, capturing radials (antioxidants), as well as demonstrating semi- and superconductive properties. According to claimed method fullerene C60 interacts with diethylaluminiumazide (Et2AlN3), taken in molar ratio C60:Et2AlN3=1:(40-60), in solution of dry toluene at -20°C in atmosphere of argon with the following heating to 40°C for 2-4 h.
EFFECT: method makes it possible to obtain novel 1-azido-2-ethyl-1,2-dihydro(C60-Ih)[5,6]fullerene of formula (1) with output to 22%.
1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDRO(C-I)[5,6]FULLERENE | 2013 |
|
RU2551279C2 |
| METHOD OF PRODUCING 1,9-(1',4'-OXATHIANO)-1,9-DIHYDRO-(C-I][5,6]FULLERENE | 2019 |
|
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| 1,9-(2'-HYDROXYMETHYL-1',4'-DIOXANO)-1,9-DIHYDRO-(C-I)[5,6]FULLERENE AND ITS PRODUCTION METHOD | 2021 |
|
RU2785546C2 |
| METHOD FOR OBTAINING 1,9-(1',4'-OXATHIANO-4'-OXIDE)-1,9-DIHYDRO-(C-I)[5,6]FULLERENE | 2022 |
|
RU2785692C1 |
| METHOD OF PRODUCING 1-IODO-2-AZIDO(C-I)[5,6]FULLERENE | 2011 |
|
RU2484010C2 |
| METHOD FOR SELECTIVE PRODUCTION OF 2',5'-UNSUBSTITUTED 1'-BENZYLPYRROLIDINO[3',4':1,9](C60-IH)[5,6]FULLERENES | 2017 |
|
RU2666726C1 |
| METHOD OF PRODUCING 1-AZIDO-2-BUTYL-1,2-DIHYDRO(C-I)[5,6]FULLERENE | 2013 |
|
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| 1,9-[3',3'-BIS(HYDROXYMETHYL)MORPHOLINO]-1,9-DIHYDRO-(C-I)[5,6]FULLERENE AS A COMPLEXING AGENT AND METHOD FOR ITS PREPARATION | 2022 |
|
RU2807926C1 |
| METHOD FOR PREPARING 1-[3-HYDROXY-3-(PYRID-4-YLPROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2294929C2 |
| METHOD OF PREPARING 1-[3-HYDROXY-3-ARYLPROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2290367C1 |
