FIELD: chemistry.
SUBSTANCE: invention relates to field of chemical technology, namely to growing crystals of potassium-barium molybdate K2Ba(MoO4)2 from solution-melt of K2Ba(MoO4)2 for analysis of physical properties and practical use. As solvent used is potassium molybdate K2MoO4, with molar ratio of potassium-barium molybdate and potassium molybdate K2MoO4, equal 1:2, respectively, crystallisation is carried out on seed, increased from 1 to 2 mm/day and rotating at rate 30-40 rev/min, oriented by direction [001], cooling of melt is carried out at rate from 0.2 to 3 degrees/day, with cooling of crystals being carried out at rate 20 degrees/day.
EFFECT: claimed method makes it possible to obtain optically homogenous K2Ba(MoO4)2, crystals of large size (25×15 mm) without inclusions, blocks and cracks.
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Authors
Dates
2015-02-10—Published
2013-04-16—Filed