FIELD: chemistry.
SUBSTANCE: invention refers to chemical technology and concerns manufacturing crystals of rubidium-bismuth molybdate RbBi(MoO4)2. The crystals RbBi(MoO4)2 are grown from a high-temperature solution in melted charge containing rubidium dimolybdate and triple lithium-rubidium-bismuth molybdate LiRbBi2(MoO4)4, in ratio of the latter toribidium dimolybdate equal to 10-40: 90-60 mole %, respectively; fuse crystallisation is focused in the direction [001], with a fuse rotation at 30-65 rpm and pulling rate 0.3-1.0 mm/day with cooling the melted solution at 0.2-1.0 degrees/day; the growing process in performed in the environment of low gradient ΔT less than 1 degrees/cm in the melted solution.
EFFECT: invention enables producing the coarse crystals RbBi(MoO4)2 of high optical quality.
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Authors
Dates
2015-02-20—Published
2013-05-22—Filed