FIELD: chemistry.
SUBSTANCE: invention can be used in chemical industry. Method of joint obtaining calcium chloride and carbon dioxide includes interaction of calcium-containing raw material, including calcium carbonate, with 20-36% hydrochloric acid, supplied in doses. Formed solution of calcium chloride CaCl2 is passed through calcium carbonate CaCO3 and/or limestone flour, with formed carbon dioxide being passed through CaCO3 or limestone flour and CaCl2. Calcium-containing raw material is subjected to interaction with 20-36% hydrochloric acid first at temperature 20-40°C with the following increase of temperature to 55-70°C. Molar ratio CaCO3 : HCl constitutes 1 : (1.8-2.2). Molar ratio of CaCO3 or limestone flour and CaCl2 constitutes 1 : (1-3).
EFFECT: invention makes it possible to increase process productivity, reduce release of harmful substances into atmosphere and sewage waters.
11 cl, 2 dwg, 3 tbl, 10 ex
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Authors
Dates
2015-04-10—Published
2013-05-29—Filed