FIELD: chemistry.
SUBSTANCE: invention relates to a method of preparing a catalyst for deep hydrofining of oil fractions. The present method includes impregnating an aluminium oxide support with a solution of compounds of metals of groups VIII and VI with pH of the impregnating solution of 1.5-5.0, vacuum treatment of the support before contact thereof with the impregnating solution, using impregnation at high temperature. The starting compounds used for preparing the impregnating solution are sodium salts Mo and one of modifiers X selected from the group (B, P, Si, V, Zn, Ge, Sn), which are soluble in water in molar ratio Mo/X=12/1, after which the solution is passed through a column with a cationite in H+ form and Co or Ni acetate is added to said solution.
EFFECT: disclosed method enables to obtain catalysts having high activity and selectivity with respect to hydrodesulfurisation, hydrodenitrogenation and hydrogenation of olefins and aromatic compounds.
2 cl, 5 tbl, 11 ex
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Authors
Dates
2015-07-10—Published
2013-09-27—Filed