FIELD: chemistry.
SUBSTANCE: method includes the preparation of a sorbent, solution of iron (III, II), addition of a hydroxylamine solution to reduce iron (III) to iron (II), extraction of iron (II) from the solution by the sorbent, transfer of iron (II) in a complex compound on the sorbent surface, separation of the sorbent from the solution, measurement of the coefficient of diffusion reflection of the surface iron (II) complex and determination of the iron content by a calibration graph, with the application as the sorbent of aluminium oxide, successively modified by polyhexamethyleneguanidine and 3-(2-pyridyl)-5,6-diphenyl-1.2,4-triazine-4',4''-disulphoacid (ferrozine), with carrying out the measurement of a diffusion reflection coefficient at 560 nm.
EFFECT: increased sensitivity and self-descriptiveness of the analysis.
4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF DETECTING IRON (II) | 2014 |
|
RU2555483C1 |
METHOD OF DETECTING IRON (II) | 2008 |
|
RU2374639C1 |
METHOD OF SEPARATING AND DETERMINING IRON (III) AND IRON (II) | 2014 |
|
RU2563984C1 |
METHOD OF DETERMINING COPPER (I) | 2021 |
|
RU2768614C1 |
METHOD OF DETECTING COPPER (I) | 2008 |
|
RU2374637C1 |
METHOD FOR DETERMINING IRON (III) | 2020 |
|
RU2755633C1 |
RUTHENIUM DETECTION METHOD | 2005 |
|
RU2287155C1 |
TERBIUM CONTENT IDENTIFICATION METHOD | 2022 |
|
RU2799630C1 |
COMPLEXING SORBENT AND METHOD OF PREPARING SAID SORBENT | 2008 |
|
RU2380152C1 |
METHOD OF DETERMINING COBALT (II) | 2011 |
|
RU2456592C1 |
Authors
Dates
2015-07-27—Published
2014-08-22—Filed