FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 1,3-dicarbonyl compounds containing a dibenzosuberenyl fragment, which are of interest as a starting compounds for synthesis of biologically active substances, as well as ligands capable of coordinating metals. The method includes reacting dibenzosuberenol and 1,3-dicarbonyl compounds at 40°C for 30-180 min in a medium of 1,2-dichloroethane or nitromethane with catalysis of 5 mol % scandium triflate.
EFFECT: method enables to obtain the desired compounds with output of 63-86%.
11 ex
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Authors
Dates
2015-08-20—Published
2014-09-22—Filed