METHOD FOR OBTAINING CATALYTICALLY ACTIVE COMPOSITE LAYERS ON ALUMINIUM ALLOY Russian patent published in 2015 - IPC B01J21/12 B01J23/72 B01J23/75 B01J23/83 B01J37/02 B01J37/25 B01J37/08 

Abstract RU 2571099 C1

FIELD: chemistry.

SUBSTANCE: invention relates to methods for production of oxide composite catalysts on metal carrier-substrate, which can be applied in reactions of CO to CO2 conversion, in purification of technological and exhaust gases, in particular, in internal-combustion engines. Method includes formation of intermediate porous layer, which contains aluminium oxide, and layer-by-layer application of metal oxide-based catalytic material, with application being realised by means of water solution, which contains components of said metal oxides in composition of salts. Aluminium oxide-containing porous layer is formed by plasma-electrolytic oxidation of substrate in silicate electrolyte, and oxide catalytically active material is applied by successive impregnation at first with Cu (II) nitrate, then Co (II) nitrate solution and in conclusion with solution of Ce (III) acetate with intermediate drying and burning of applied layers for not less than 4 h at temperature 450-550°C.

EFFECT: increase of mechanical durability of obtained composite catalysts with simultaneous simplification of method due to reduced number of operations.

2 cl, 2 dwg, 2 ex

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RU 2 571 099 C1

Authors

Tyrina Larisa Mikhajlovna

Rudnev Vladimir Sergeevich

Lukijanchuk Irina Viktorovna

Vasil'Eva Marina Sergeevna

Dates

2015-12-20Published

2014-12-24Filed