FIELD: chemistry.
SUBSTANCE: invention relates to the methods for producing oxide catalysts on a metal support substrate that can be used in oxidation reactions of CO to CO2, which take place in the high-temperature processes for cleaning process and exhaust gases, in particular in the energy and automotive industries. The proposed method includes anodizing an aluminium substrate in a galvanostatic mode at the current density of 10-15 mA/cm2 for 20-60 min in 3% aqueous solution of oxalic acid C2H2O4, washing and drying, after which the intermediate porous alumina layer formed on the aluminium substrate is treated with a 1% solution of phosphoric acid heated up to 35°C, washed, dried, and applied to the treated aluminium substrate, ultrafine manganese dioxide, which is formed by impregnation with a 5% solution of potassium permanganate KMnO4 followed by annealing in air at 220-230°C for 10 minutes, while the operation of applying manganese dioxide can be carried out three times.
EFFECT: simplification and cheaper technology while expanding the range of composite catalytic materials containing a metal substrate with supported transition metal oxides.
2 cl, 4 dwg, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR FORMING HYBRID COATING ON ALUMINUM | 2023 |
|
RU2796602C1 |
METHOD FOR OBTAINING CATALYTICALLY ACTIVE COMPOSITE LAYERS ON ALUMINIUM ALLOY | 2014 |
|
RU2571099C1 |
METHOD OF PREPARING CATALYTICALLY ACTIVE LAYERS AND CATALYTICALLY ACTIVE MATERIAL PREPARED BY THIS METHOD | 1998 |
|
RU2152255C1 |
METHOD OF PRODUCING OXIDE CATALYTICALLY ACTIVE SURFACE LAYERS OF VALVE METAL OR ITS ALLOY | 2012 |
|
RU2500474C1 |
METHOD OF PRODUCING PROTECTIVE ANTICORROSION COATINGS ON ALUMINUM ALLOYS WITH WELDED SEAMS | 2019 |
|
RU2703087C1 |
METHOD FOR PRODUCING SUPERHYDROPHOBIC COATINGS ON MAGNESIUM-CONTAINING ALUMINUM ALLOYS | 2020 |
|
RU2747434C1 |
METHOD OF PRODUCING PROTECTIVE COATINGS ON MAGNESIUM-CONTAINING ALLOYS OF ALUMINUM | 2020 |
|
RU2734426C1 |
METHOD OF PRODUCING SUPER-HYDROPHOBIC COATINGS WITH ANTI-ICING PROPERTIES ON ALUMINUM AND ITS ALLOYS | 2019 |
|
RU2707458C1 |
METHOD FOR PRODUCING CARBON MATRIX NANOSTRUCTURED COMPOSITE | 2022 |
|
RU2790222C1 |
OZONE DECOMPOSITION CATALYST AND METHOD FOR PREPARATION THEREOF | 2013 |
|
RU2537300C1 |
Authors
Dates
2018-01-17—Published
2017-01-10—Filed