METHOD FOR OBTAINING 2,2-BIS[4-(4-NITROPHENOXY]PHENYL]HEXAFLUOROPROPANE UNDER INFLUENCE OF ULTRASOUND Russian patent published in 2016 - IPC C07C201/12 C07C205/38 

Abstract RU 2577544 C1

FIELD: chemistry.

SUBSTANCE: invention relates to method for obtaining 2,2-bis[4-(4-nitrophenoxy)phenyl]hexafluoropropane of formula , given below, which finds application as semi-product in synthesis of monomer for obtaining polymers, under influence of ultrasound. Method includes interaction of 2,2-bis(4-hydroxyphenyl)hexafluoropropane with 4-nitrochlorobenzene with ultrasound activation. Aromatic nucleophilic substitution of chlorine atom is carried out in DMSO in presence of K2CO3 at ultrasound frequency 37 kHz, and temperature 80°C for 1 h at molar ratio 4-nitrochlorobenzene:2,2-bis(4-hydroxyphenyl)hexafluoropropane = 1:0.5.

EFFECT: method makes it possible to reduce time and temperature of reaction of aromatic nucleophilic substitution and increase output and purity of obtained product.

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RU 2 577 544 C1

Authors

Begunov Roman Sergeevich

Valjaeva Asja Nikolaevna

Chervonogorodskaja Ekaterina Igorevna

Dobretsova Natalja Olegovna

Beljaev Vitalij Vladimirovich

Dates

2016-03-20Published

2015-03-11Filed