FIELD: chemistry.
SUBSTANCE: invention relates to a method of preparing cobalt-bearing hydrocarbon synthesis catalyst precursor, which involves calcining loaded catalyst carrier, which is a catalyst carrier for application of cobalt salt, application of cobalt salt medium and further decomposition of cobalt salt and/or cobalt salt reaction with oxygen; so, that when firing a cobalt salt is converted to cobalt oxide, the calcination includes heating of catalyst carrier with a salt at temperature 90-220 °C, using one or more periods of fast heating at the specified temperature range, note here that heating of catalyst carrier with a salt takes place at a rate of at least 10 °C/min at a rate of gas flow through the catalyst carrier with a salt of at least 5 m3 n/kg of salt of cobalt/h; one or more periods of slow heating at the specified temperature range, besides, heating the catalyst carrier with a salt takes place at a rate of less than 6 °C/min for calcining salt of cobalt and cobalt-containing precursor preparation of catalysts for synthesis of hydrocarbons. Invention also relates to a method of preparing catalyst for synthesis of hydrocarbons and to a method for synthesis of hydrocarbons.
EFFECT: technical result is obtaining a catalyst with fine crystalline particles and/or with high activity.
21 cl, 5 tbl, 21 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYSTS | 2012 |
|
RU2591702C2 |
METHOD OF FISCHER-TROPSCH SYNTHESIS COBALT-CONTAINING CATALYST PRODUCING | 2012 |
|
RU2602803C2 |
METHOD FOR PRODUCING COBALT-CONTAINING CATALYST PRECURSOR AND METHOD FOR HYDROCARBON SYNTHESIS | 2019 |
|
RU2796695C2 |
METHOD OF CLEANING OF LITHIUM-7 HYDROXIDE | 2000 |
|
RU2252072C2 |
CATALYSTS | 2011 |
|
RU2551433C1 |
METHOD OF REGENERATING FISCHER-TROPSCH SYNTHESIS COBALT CATALYST | 2008 |
|
RU2456080C2 |
CATALYSTS | 2010 |
|
RU2517700C2 |
METHOD OF PREPARING SUPPORTED COBALT-BASED FISCHER-TROPSCH SYNTHESIS CATALYST | 2008 |
|
RU2456329C2 |
METHOD OF PRODUCING FISCHER-TROPSCH SYNTHESIS CATALYST | 2009 |
|
RU2481156C2 |
METHOD OF PRODUCING FISCHER-TROPSH SYNTHESIS OXIDE COBALT-ZINC CATALYST | 2008 |
|
RU2501605C2 |
Authors
Dates
2016-07-20—Published
2012-04-25—Filed