METHOD FOR PRODUCING 2-HYDROXY-4-(METHYLTHIO)BUTANENITRILE FROM 3-(METHYLTHIO)PROPANAL AND HYDROGEN CYANIDE Russian patent published in 2016 - IPC C07C319/20 C07C319/28 C07C323/52 C07B61/00 C07C319/26 C07C323/12 C07C323/60 C07C323/58 

Abstract RU 2604534 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method for producing 2-hydroxy-4-(methylthio)butanenitrile, wherein 3-(methylmercapto)-propionaldehyde is reacted with hydrogen cyanide in presence of a base as catalyst into nitrile in a main reaction zone, and residual gaseous hydrogen cyanide quantities that exit main reaction zone are absorbed in an absorption- and post-reaction zone containing a mixture of 3-(methylmercapto)-propionaldehyde and catalyst, as well as optionally 2-hydroxy-4-(methylthio)butanenitrile and subjected to further conversion with 3-(methylmercapto)-propionaldehyde with subsequent removal of product, containing 2-hydroxy-4-(methylthio)butanenitrile, where in output product molar ratio between hydrogen cyanide and unreacted 3-(methylmercapto)-propionaldehyde is greater than 1.

EFFECT: method enables to obtain storage-stable during storage cyanohydrin and increases output of end product.

24 cl, 1 dwg, 2 ex

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Authors

Buss Diter

Shtojrentkhaler Martin

Rinner Mikhael R.

Kretts Shtefan

Khasselbakh Khans Joakhim

Finkeldaj Kaspar-Genrikh

Kerfer Martin

Tsakki Pablo

Dates

2016-12-10Published

2012-02-13Filed