FIELD: chemistry.
SUBSTANCE: method is proposed for preparing catalysts based on boron-containing silicates of a zeolite structure having a boron content of less than 1 wt %, comprising preparing an aqueous slurry containing, at least, one boron-containing silicate with a MFI type zeolite structure having a SiO2/B2O3 from 2 to 4 and an aluminium content of less than 1 wt %; additing acid to establish a pH of 1-5; stirring the slurry; isolating the resulting solid, its optional washing and calcinating at a temperature not higher than 350°C. A catalyst is proposed, prepared by the inventive process.
EFFECT: proposed catalysts provide a high level of selectivity to isobutene during the cleavage of methyl-tertio-butyl ether and provide a reduced formation of by-products.
15 cl, 2 ex
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Authors
Dates
2017-08-14—Published
2013-09-24—Filed