FIELD: chemistry.
SUBSTANCE: compound is used as a motor fuel dope. The method consists in N-alkylation of para-anisidine with dimethyl carbonate at a mole ratio of dimethyl carbonate: para-anisidine 0.5-1.0:1.0 The process is carried out in the gas phase at a temperature of 180-260°C, preferably 180-220°C, in the presence of a dehydrogenation catalyst in a stream of nitrogen or hydrogen. The catalyst used in the process comprises wt %: CuO 10-60; NiO 0-40; ZnO 10-60; Cr2O3 0-20; Al2O3 - is the rest. The obtained product is extracted by rectification.
EFFECT: method allows to obtain a product with a yield relative to the para-anisidine and a content of the basic substance of at least 97 percent.
2 tbl, 32 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE | 2011 |
|
RU2472774C1 |
| METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-PHENETIDINE | 2011 |
|
RU2471771C1 |
| METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE | 2012 |
|
RU2508288C1 |
| ANTIDETONATING ADDITIVE ON THE BASIS OF MIXTURE OF METHYLATED TOLUIDINES AND METHOD OF SELECTIVE RECEIVING OF MIXTURE OF N-METHYL-TOLUIDINES | 2015 |
|
RU2659221C2 |
| METHOD OF SYNTHESIS OF N-ALKYLANILINES | 1998 |
|
RU2152382C1 |
| METHOD FOR PRODUCTION OF N-METHYL ANILINE | 1995 |
|
RU2066679C1 |
| METHOD OF PRODUCING N-METHYL-PARA-ANISIDINE | 2016 |
|
RU2632813C1 |
| METHOD OF PRODUCING N-METHYL-PARA-PHENETIDINE | 2016 |
|
RU2632880C1 |
| CATALYST, PREPARATION METHOD THEREOF AND METHOD OF FLUORINATING HALOGENATED HYDROCARBONS | 2009 |
|
RU2402378C1 |
| CATALYST AND METHOD OF OBTAINING N-METHYLANILINE | 2007 |
|
RU2346740C1 |
