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2 638 043

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A01N37/46(2006-01-01)

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2015129530, 2013-12-18

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2013-12-18

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2013-12-18

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2017-12-11

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Inventor

Lo Villyam K.Khanter Dzhejms E.Uotson Dzherald B.Patni AkshajIjer Pravin S.Boruva Dzhoshodip

(73)

Holder

Dau Agrosajensiz Elelsi

PESTICIDE COMPOSITIONS AND RELATED METHODS Russian patent published in 2017 - IPC A01N37/46 

Abstract RU 2638043 C2

FIELD: agriculture.

SUBSTANCE: composition includes a molecule according to Formula One:

,

where: (a) R1 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo (C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8) alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl), N(R14)(R15), (2) substituted (C1-C8)alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, (3) substituted halo(C1-C8) alkyl, where the said substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, (4) substituted (C1-C8)alkoxy, where the substituted (C1-C8)alkoxy has one or more substituents selected from CN and NO2, and (5) substituted halo (C1-C8)alkoxy, where the substituted halo(C1-C8)alkoxy has one or more substituents selected from CN and NO2; (b) R2 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8) alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8)alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl), N(R14)(R15), (2) substituted (C1-C8)alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, (3) substituted halo(C1-C8)alkyl, where the substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2,(4) substituted (C1-C8)alkoxy, where the substituted (C1-C8)alkoxy has one or more substituents selected from CN and NO2, and (5) substituted halo(C1-C8)alkoxy, where the substituted halo(C1-C8)alkoxy has one or more substituents selected from CN and NO2; (c) R3 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8)alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl), N(R14)(R15), (2) substituted (C1-C8)alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, (3) substituted halo(C1-C8)alkyl, where the substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, (4) substituted (C1-C8)alkoxy, where the substituted (C1-C8)alkoxy has one or more substituents selected from CN and NO2, and (5) substituted halo(C1-C8)alkoxy, where the substituted halo(C1-C8)alkoxy has one or more substituents selected from CN and NO2; (d) R4 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8)alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl), N(R14)(R15), (2) substituted (C1-C8)alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, (3) substituted halo(C1-C8)alkyl, where the substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, (4) substituted (C1-C8)alkoxy, where the substituted (C1-C8)alkoxy has one or more substituents selected from CN and NO2, and (5) a substituted halo(C1-C8)alkoxy, where the substituted halo (C1-C8)alkoxy has one or more substituents selected from CN and NO2; (e) R5 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8)alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl), N(R14)(R15), (2) substituted (C1-C8)alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, (3) substituted halo(C1-C8)alkyl, where the substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, (4) substituted (C1-C8)alkoxy, where the substituted (C1-C8)alkoxy has one or more substituents selected from CN and NO2, and (5) substituted halo(C1-C8)alkoxy, where the substituted halo(C1-C8)alkoxy has one or more substituents selected from CN and NO2; (f) R6 is (C1-C8)haloalkyl; (g) R7 is selected from H, F, Cl, Br, I, OH, (C1-C8)alkoxy and halo(C1-C8)alkoxy; (h) R8 is selected from H, (C1-C8)alkyl, halo(C1-C8)alkyl, OR14 and N (R14) (R15); (i) R9 is selected from H, F, Cl, Br, I, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, OR14 and N (R14) (R15); (j) R10 is selected from: (1) H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, cyclo(C3-C6)alkyl, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), S(O)(C1-C8)alkyl, S(O)(halo(C1-C8)alkyl), S(O)2(C1-C8)alkyl, S(O)2(halo(C1-C8)alkyl, NR14R15, C(=O)H, C(=O)N(R14)(R15), CN(R14)(R15)(=NOH), (C=O)O(C1-C8)alkyl, (C=O)OH, heterocyclyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, (2) substituted (C1-C8) alkyl, where the substituted (C1-C8)alkyl has one or more substituents selected from OH, (C1-C8)alkoxy, S(C1-C8)alkyl, S(O)(C1-C8)alkyl, S(O)2(C1-C8)alkyl, NR14R15, and (3) substituted halo(C1-C8)alkyl, where the substituted halo(C1-C8)alkyl has one or more substituents selected from (C1-C8)alkoxy, S(C1-C8)alkyl, S(O)(C1-C8)alkyl, S(O)2(C1-C8)alkyl and N(R14)(R15); (k) R11 is a C(=X5)N(H)((C0-C8)alkyl)N(R11a)(C(=X5)(R11b)), where each X5 is independently selected from O or S, and where each R11a is independently selected from H, (C1-C8)alkyl, substituted (C1-C8)alkyl, halo(C1-C8)alkyl, substituted halo(C1-C8)alkyl, cyclo(C3-C8)alkyl and substituted cyclo(C3-C8)alkyl, where each substituted (C1-C8)alkyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, OC(=O)H, OH, S(C1-C8)alkyl, S(O)(C1-C8)alkyl, S(O)2(C1-C8)alkyl, OS(O)2aryl, N((C1-C8)alkyl)2 (where each (C1-C8) alkyl is selected independently), aryl, substituted aryl, heterocyclyl, substituted heterocyclyl, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8alkoxy), S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) alkyl is selected independently) and oxo, where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently), C(=O)(C1-C8)alkyl, C(=O)(C3-C6)cycloalkyl, S(=O)2(C1-C8)alkyl, NR14R15 and oxo, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently) and oxo, where each substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where the substituted (C3-C8)alkyl has one or more substituents selected from CN and NO2, where each R11b is independently selected from (C1-C8)alkyl, substituted (C1-C8)alkyl, halo(C1-C8)alkyl, substituted halo(C1-C8)alkyl, cyclo(C3-C8)alkyl, substituted cyclo(C3-C8)alkyl, (C2-C8)alkenyl and (C2-C8)alkynyl, where each substituted (C1-C8)alkyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, OC(=O)H, OH, S(C1-C8)alkyl, S(O)(C1-C8)alkyl, S(O)2(C1-C8)alkyl, OS(O)2aryl, N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently), aryl, substituted aryl, heterocyclyl, substituted heterocyclyl, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8), alkyl is selected independently) and oxo, where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently), C(=O)(C1-C8)alkyl, C(=O)(C3-C6)cycloalkyl, S(=O)2(C1-C8)alkyl, NR14R15 and oxo, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently) and oxo, where the substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where the substituted cyclo(C3-C8)alkyl has one or more substituents selected from CN and NO2; (1) R12 is selected from (v), H, F, Cl, Br, I, CN, (C1-C8) alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy and cyclo(C3-C6)alkyl; (m) R13 is selected from (v), H, F, Cl, Br, I, CN, (C1-C8) alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy and halo(C1-C8)alkoxy; (n) each R14 is independently selected from H, (C1-C8)alkyl, (C2-C8)alkenyl substituted (C1-C8)alkyl, halo(C1-C8) alkyl, substituted halo(C1-C8)alkyl, (C1-C8)alkoxy, cyclo(C3-C6)alkyl, aryl, substituted aryl, (C1-C8)alkyl-aryl, (C1-C8)alkyl-(substituted aryl), O-(C1-C8)alkyl-aryl, O-(C1-C8)alkyl-(substituted aryl), heterocyclyl, substituted heterocyclyl, (C1-C8)alkyl-heterocyclyl, (C1-C8) alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl-heterocyclyl, O-(C1-C8)alkyl-(substituted heterocyclyl), N(R16)(R17), (C1-C8)alkyl-C(=O)N(R16)(R17), C(=O)(C1-C8)alkyl, C(=O)(halo(C1-C8)alkyl), C(=O)(C3-C6)cycloalkyl, (C1-C8)alkyl-C(=O)O(C1-C8)alkyl, C(=O)H, where each substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8) alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo (C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) is selected independently) and oxo, and where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8) alkoxy, (C3-C6)cycloalkyl, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently), heterocyclyl, C(=O)(C1-C8)alkyl, C(=O)O(C1-C8)alkyl and oxo, (where the said alkyl, alkoxy and heterocyclyl may be further substituted by one or more F, Cl, Br, I, CN and NO2); (o), each R15 is independently selected from H, (C1-C8)alkyl, (C2-C8)alkenyl substituted (C1-C8)alkyl, halo(C1-C8)alkyl, substituted halo(C1-C8)alkyl, (C1-C8)alkoxy, cyclo(C3-C6)alkyl, aryl, substituted aryl, (C1-C8)alkyl-aryl, (C1-C8)alkyl-(substituted aryl), O-(C1-C8)alkyl-aryl, O-(C1-C8)alkyl-(substituted aryl), heterocyclyl, substituted heterocyclyl, (C1-C8)alkyl-heterocyclyl, (C1-C8)alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl-heterocyclyl, O-(C1-C8)alkyl-(substituted heterocyclyl), N(R16)(R17), (C1-C8)alkyl-C(=O)N(R16)(R17), C(=O)(C1-C8)alkyl, C(=O)(halo (C1-C8)alkyl), (=O)(C3-C6)cycloalkyl, (C1-C8)alkyl-C(=O)O(C1-C8)alkyl, C(=O)H, where each substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) alkyl is selected independently) and oxo, and where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8) alkoxy, (C3-C6)cycloalkyl, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) alkyl is selected independently), heterocyclyl, C(=O)(C1-C8)alkyl, C(=O)O(C1-C8) alkyl and oxo, (where the said alkyl, alkoxy and heterocyclyl may be further substituted by one or more F, Cl, Br, I, CN and NO2); (p), each R16 is independently selected from H, (C1-C8)alkyl, substituted (C1-C8)alkyl, halo(C1-C8)alkyl, substituted halo(C1-C8)alkyl, cyclo(C3-C6)alkyl, aryl, substituted aryl, (C1-C8)alkyl-aryl, (C1-C8)alkyl-(substituted aryl), O-(C1-C8)alkyl-aryl, O-(C1-C8)alkyl-(substituted aryl), heterocyclyl, substituted heterocyclyl, (C1-C8)alkyl-heterocyclyl, (C1-C8)alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl-heterocyclyl, O-(C1-C8)alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl, where each substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) is selected independently) and oxo, and where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo (C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8) alkyl is selected independently) and oxo; (q), each R17 is independently selected from H, (C1-C8)alkyl, substituted (C1-C8)alkyl, halo(C1-C8)alkyl, substituted halo(C1-C8)alkyl, cyclo(C3-C6)alkyl, aryl, substituted aryl, (C1-C8)alkyl-aryl, (C1-C8)alkyl-(substituted aryl), O-(C1-C8)alkyl-aryl, O-(C1-C8)alkyl-(substituted aryl), heterocyclyl, substituted heterocyclyl, (C1-C8)alkyl-heterocyclyl, (C1-C8)alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl-heterocyclyl, O-(C1-C8)alkyl-(substituted heterocyclyl), O-(C1-C8)alkyl, where each substituted (C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted halo(C1-C8)alkyl has one or more substituents selected from CN and NO2, where each substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently) and oxo, and where each substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, halo(C1-C8)alkyl, (C1-C8)alkoxy, halo(C1-C8)alkoxy, S(C1-C8)alkyl, S(halo(C1-C8)alkyl), N((C1-C8)alkyl)2 (where each (C1-C8)alkyl is selected independently) and oxo; (r) X1 is selected from N and CR12; (s) X2 is selected from N, CR9 and CR13; (t) X3 is selected from N and CR9; and (v) R12 and R13 together form a link that contains 3-4 atoms selected from the C, N, J and S, where the specified link connects back to the ring, forming a 5-6-membered saturated or non-saturated cyclic ring where the specified link has at least one X4 substituent, where X4 is selected from R14, N(R14)(R15), N(R14)(C(=O)R14), N(R14)(C(=S)R14), N(R14)(C(=O)N(R14)(R14)), N(R14)(C(=S)N(R14)(R14)), N(R14)(C(=O)N(R14)((C2-C8)alkenyl), N(R14)(C(=S)N(R14)((C2-C8)alkenyl), where each R14 is selected independently.

EFFECT: increased effectiveness of pest control.

72 cl, 9 tbl, 136 ex

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RU 2 638 043 C2

Authors

Lo Villyam K.

Khanter Dzhejms E.

Uotson Dzherald B.

Patni Akshaj

Ijer Pravin S.

Boruva Dzhoshodip

Dates

2017-12-11—Published

2013-12-18—Filed

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