METHOD FOR PRODUCING ENDO-ENDO-HEXACYCLO[9,2,1,0,0,0,0]TETRADECENE-12 Russian patent published in 2017 - IPC C07C2/42 C07C13/64 

Abstract RU 2640204 C2

FIELD: chemistry.

SUBSTANCE: invention relates to the method for producing dimer of norbornadiene-endo-endo-hexacyclo[9.2.1.02.10.03.8.04.6.05.9]tetradecene-12 by dimerization of norbornadiene under the action of the catalytic system Fe (acac)3-AlEt3-CH2(CN)2 at the molar ratio of catalyst and reagent [Fe(acac)3]:[CH2(CN)2]:[AlEt3]:[norbornadiene]=1:1÷6:6÷10:100÷200 in toluene, at 110°C for 0.2 h. With complete conversion of norbornadiene, the yield of endo-endo-hexacyclo[9.2.1.02,10.03.8.04.6.05.9]tetradecene-12 reaches 93%.

EFFECT: increasing the yield.

1 tbl, 12 ex

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RU 2 640 204 C2

Authors

Dzhemilev Usein Memetovich

Khusnutdinov Ravil Ismagilovich

Aminov Rishat Ishbirdovich

Tomilov Yurij Vasilevich

Nefedov Oleg Matveevich

Kurbatov Vadim Evgenevich

Vinogradova Marina Evgenevna

Tupakhina Elena Aleksandrovna

Dates

2017-12-27Published

2015-12-31Filed