FIELD: chemistry.
SUBSTANCE: invention relates to boron-fluoride-containing compositions that can be used as high-calorie components of energy condensed systems (ECS), for example, powders, pyrotechnic and explosive compositions, mixed solid rocket fuels, and the like. The boron-fluoride-containing energy-intensive composition for energy condensed systems contains dodecahydro-closo-dodecaborate of chitosan (C6O4H9NH3)2B12H12and as an oxygen oxidant, chitosan C6O4H9NH3ClO4 and further comprises ultrafine polytetrafluoroethylene (UPTFE) in an amount providing the completeness and rate of boron transfer of the borohydride compound to boron oxofluoride (BOF)3. The composition is prepared by mixing freshly precipitated, moist dodecahydro-closo-dodecaborate of chitosan, an aqueous gel of chitosan and UPTHE in the form of ethanol dispersion in an appropriate amount to a homogeneous gel, thus the optimal molar ratio of dodecahydro-closo-dodecaborate of chitosan: chitosan perchlorate: UPTFE is 1:1:3.
EFFECT: invention provides for obtaining homogeneous boron-fluoride-containing energy-intensive compositions that are distinguished by the completeness of combustion and are promising for their use as high-calorie components of energy compensated systems.
6 cl, 7 ex
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Authors
Dates
2017-12-27—Published
2017-02-02—Filed