FIELD: power engineering.
SUBSTANCE: invention relates to compositions containing boron and fluorine, which can be used as high-energy components of energy condensed systems (ECS), for example, gunpowders, pyrotechnic and explosive compounds, composite solid propellants. Energy rich compositions containing boron and fluorine contains as fuel -intercalate compound of graphite oxide with dodecahydro-closo-dodecaborate compound with molar ratio 1 to (0.1–0.3) and as oxidising agent – ultrafine polytetrafluoroethylene (PTFE) in amount ensuring completeness and rate of boron transition form borohydride compound into boron oxyfluoride (BOF)3, herewith dodecahydro-closo-dodecaborate compound is ammonia salt of ammonium dodecahydro-closo-dodecahydrate (NH4)2B12H12. Composition is obtained by mixing fuel in the form of graphite oxide aqueous gel and aqueous solution of ammonium dodecahydro-closo-dodecanitrate with molar ratio of 1 to (0.1–0.3) with PTFE as oxidising agent in the form of ethanol dispersion in the specified quantity till homogeneous gel. Then the produced mixture is dried to constant mass.
EFFECT: invention provides simpler method and allows to obtain thermally more stable energy-rich composition.
2 cl, 4 ex
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Authors
Dates
2017-02-14—Published
2015-11-24—Filed